| Second Round | 1 | 2 | |||
| 3 Andrey Rublev | 6 | 6 | |||
| Federico Gaio | 4 | 3 | |||
| Winner: Andrey Rublev | |||||
| Second Round | 1 | 2 | 3 | ||
| 10 Felix Auger-Aliassime | 4 | 6 | 6 | ||
| Lorenzo Musetti | 6 | 3 | 0 | ||
| Winner: Felix Auger-Aliassime | |||||
| Second Round | 1 | 2 | |||
| 17 Adrian Mannarino | 4 | 4 | |||
| Albert Ramos-Vinolas | 6 | 6 | |||
| Winner: Albert Ramos-Vinolas | |||||
| Second Round | 1 | 2 | |||
| 14 Alex De Minaur | 77 | 6 | |||
| Alexander Bublik | 63 | 2 | |||
| Winner: Alex De Minaur | |||||
| Second Round | 1 | 2 | |||
| 2 Stefanos Tsitsipas | 6 | 6 | |||
| Jaume Munar | 0 | 2 | |||
| Winner: Stefanos Tsitsipas | |||||
| Second Round | 1 | 2 | |||
| 6 Pablo Carreno Busta | 6 | 6 | |||
| Jordan Thompson | 4 | 0 | |||
| Winner: Pablo Carreno Busta | |||||
| Second Round | 1 | 2 | |||
| 16 Daniel Evans | 4 | 2 | |||
| Corentin Moutet | 6 | 3 | |||
| In-Progress | |||||
| Second Round | 1 | 2 | |||
| 9 Fabio Fognini | 0 | 0 | |||
| Bernabe Zapata Miralles | 6 | 0 | |||
| In-Progress | |||||
| Second Round | |||||
| 1 Rafael Nadal | |||||
| Ilya Ivashka | |||||
| Pre-Match | |||||
| Second Round | |||||
| 13 Cristian Garin | |||||
| Kei Nishikori | |||||
| Pre-Match | |||||
| Second Round | |||||
| 4 Diego Schwartzman | |||||
| Frances Tiafoe | |||||
| Pre-Match | |||||
| Second Round | 1 | 2 | 3 | ||
| 8 Miomir Kecmanovic | 6 | 3 | 6 | ||
| Arthur Rinderknech | 3 | 6 | 3 | ||
| Winner: Miomir Kecmanovic | |||||
| Second Round | |||||
| 1 Novak Djokovic | |||||
| Soon Woo Kwon | |||||
| Pre-Match | |||||
| Second Round | |||||
| 2 Matteo Berrettini | |||||
| Marco Cecchinato | |||||
| Pre-Match | |||||
| Second Round | |||||
| 5 Filip Krajinovic | |||||
| Nikola Milojevic | |||||
| Pre-Match | |||||
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